The description for terminology says:
Topics related to the body of terms used with a particular technical application in a subject of study, theory, profession, etc.
I think the difference is that in one case, you are asking about a technical term, and when to use it (terminology); in the other case, you want to use a single word instead of a phrase, and you ask which word to use describing the context.
So, when you ask when the term metonymy is used, the tag should be terminology, but when you ask for a single word to use instead of "fantastic event that leaves you in a such catatonic state that somebody could steal the chair you are sitting on without you noticing it," that should be tagged single-word-request.
As you are referring to another question that is tagged terminology in your own question, I think it should be tagged with the same tag.